Rationalism should not be confused with rationality, nor with rationalization.
-Wikipedia article on rationalism
I frequently see people using rationalism in place of rationality. Usually other commenters understand them, however I believe that using the word rationality is superior. The Less Wrong tag line is "A community blog devoted to refining the art of human rationality". On the other hand, rationalism is the philosophical term for a very different epistemological position. Furthermore, -the -ism suffix has some undesirable connotations.
Your claim seemed wrong to me, so I did a LW google search for "rationalism" and got 10 pages of results. There were about 13 results from 2013 (including this post.) I didn't look carefully but it seems at least a few of these incidents were using the word correctly. So with all the content posted on LW, "rationalism" is misused perhaps once every few weeks. It's basically a rare typo, not something worth a discussion post.